참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Dimethylamine | HCID 674 | — |
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Carbon Disulfide | HCID 6348 | — |
| 용매 | Isopropanol | HCID 3776 | — |
| 생성물 | Thiram | HCID 5455 | 98.6% |
반응 단계
13.5 g (0.3 mol) of dimethylamine and 24.4 mg (0.1×10-3 mol) of Mn(CH3COO)2.4H2O were dissolved in 100 g of isopropanol in the reaction equipment described in Example 1. 22.8 g (0.3 mol) of carbon disulfide were added to this solution. The resulting clear, dark brown solution was heated to 50° C., stirred vigorously, and subjected to 1.7 bar of oxygen. Under these conditions, the reaction came to an end after 90 minutes. TMTD was obtained with a yield of 98.6%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04459424 |
|---|
| 출처 데이터셋 | uspto-grants-1984_07 |
|---|
| ORD ID | ord-4a7a25c6d1f64aa2af5c0362cf7b9df1 |
|---|
| 출처 메모 | uspto-grants-1984_07 |
|---|
