反应详情

温度

50 °C

13.5 g (0.3 mol) of dimethylamine and 24.4 mg (0.1×10-3 mol) of Mn(CH3COO)2.4H2O were dissolved in 100 g of isopropanol in the reaction equipment described in Example 1. 22.8 g (0.3 mol) of carbon disulfide were added to this solution. The resulting clear, dark brown solution was heated to 50° C., stirred vigorously, and subjected to 1.7 bar of oxygen. Under these conditions, the reaction came to an end after 90 minutes. TMTD was obtained with a yield of 98.6%.