Benzoyl Peroxide → Methanone, [2-(bromomethyl)phenyl]phenyl-

HRID 1463533

반응식

HRID 1463533 반응식
[CH3:1][C:2]1[CH:15]=[CH:14][CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5].[Br:16]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:16][CH2:1][C:2]1[CH:15]=[CH:14][CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5]

참가 물질

5

반응물 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 672302-Methylbenzophenone

생성물 1

HCID 11778133Methanone, [2-(bromomethyl)phenyl]phenyl-

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

실험 절차

A mixture of 2-methylbenzophenone (9.8 g), N-bromosuccinimide (8.9 g), benzoyl peroxide (0.5 g) and carbon tetrachloride (150 ml) was refluxed for 1 hour with light irradiation. The mixture was cooled, and then filtered to remove insoluble substances. The filtrate was concentrated to afford quantitatively the above-titled compound as an oily substance.

후처리

  1. temperaturewas refluxed for 1 hour with light irradiation
  2. temperatureThe mixture was cooled
  3. filtrationfiltered
  4. customto remove insoluble substances
  5. concentrationThe filtrate was concentrated

출처 및 근거

ORD 기록
ord-3064d57c8434463a8dcd29dda0dbc922
출처 데이터셋
uspto-grants-1994_04
특허 번호
US05300646

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