2-Oxobutanoic Acid → L-Aspartic Acid

HRID 1464623노트

반응식

HRID 1464623 반응식
O=C(CC)C(O)=O.O=C(CCC)C(O)=O.CC(C)CC(=O)C(O)=O.O[CH:26]([C:32]([OH:34])=[O:33])[C@@H:27]([C:29]([OH:31])=[O:30])[NH2:28]>>[NH2:28][C@H:27]([C:29]([OH:31])=[O:30])[CH2:26][C:32]([OH:34])=[O:33]

참가 물질

5

반응물 4

HCID 582-Oxobutanoic AcidHCID 704-Methyl-2-oxovaleric acidHCID 745632-Oxovaleric acidHCID 4401753-hydroxy-L-aspartic acid

생성물 1

HCID 5960L-Aspartic Acid

실험 절차

β-hydroxy, aspartic acid derviatives 12b-d were prepared from copperglycinate and 2-oxobutanoic acid, 2-oxopentanoic acid and 4-methyl,2-oxopentanoic acid, respectively, according to the procedure described by L. Benoiton et al. (J. Am. Chem. Soc, 81, 1726-1729, 1959). β-Hydroxyaspartic acid was obtained from Sigma Chem. Comp.

출처 및 근거

ORD 기록
ord-decc8a782cdc4395a9b7b6cc2b008839
출처 데이터셋
uspto-grants-1994_04
특허 번호
US05306809

반응 노트

불러오는 중…