4-Hydroxybenzaldehyde → HCID 178501257, 화합물

HRID 1485099노트

반응식

OC1C=CC(C=O)=CC=1.C1(CCO)CC1.[C:16]1([OH:22])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.O[C@@H:24]1[CH2:29][CH2:28][C@H:27]([C:30]([O:32][CH3:33])=[O:31])[CH2:26][CH2:25]1>>[O:22]([C@H:24]1[CH2:29][CH2:28][C@H:27]([C:30]([O:32][CH3:33])=[O:31])[CH2:26][CH2:25]1)[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1

참가 물질

반응물 4

HCID 1264-Hydroxybenzaldehyde

HCID 996Phenol

HCID 1376422-Cyclopropylethan-1-ol

HCID 178501284HCID 178501284, 화합물

생성물 1

HCID 178501257HCID 178501257, 화합물수율 44.9%

실험 절차

Instead of 4-hydroxybenzaldehyde and 2-cyclopropylethanol, phenol (1.43 g) and methyl cis-4-hydroxycyclohexanecarboxylate (2.00 g) were respectively used and treated by the same technique as in Reference Example 11-1 to give methyl trans-4-phenoxycyclohexanecarboxylate as a colorless oil (1.33 g).

후처리

additiontreated by the same technique as in Reference Example 11-1

출처 및 근거

ORD 기록: ord-c23eedd4fc894509a899d44b497a8f48
출처 데이터셋: uspto-grants-2016_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09422240B2

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