Sodium Sulfite → Sodium 4-benzyloxyphenethyl sulfonate
반응식
[CH2:1]([O:8][C:9]1[CH:17]=[CH:16][C:12]([CH2:13][CH2:14]Br)=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[S:18]([O-:21])([O-:20])=[O:19].[Na+:22].[Na+]>C(O)(C)(C)C.O>[CH2:1]([O:8][C:9]1[CH:17]=[CH:16][C:12]([CH2:13][CH2:14][S:18]([O-:21])(=[O:20])=[O:19])=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Na+:22]참가 물질
5
실험 절차
A mixture of 4-benzyloxyphenethyl bromide (11.8 g) and sodium sulfite (8.91 g) in tert-butyl alcohol (40 ml) and water (80 ml) is heated at reflux for 40 hours, cooled to room temperature, filtered and the solid washed with water and ether to give sodium 4-benzyloxyphenethyl sulfonate.
후처리
- temperatureis heated
- temperatureat reflux for 40 hours
- filtrationfiltered
- washthe solid washed with water and ether
출처 및 근거
- ORD 기록
- ord-124122ce245f4bb1baab17b15b92627f
- 출처 데이터셋
- uspto-grants-1997_10
- 특허 번호
- US05674482
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