(Ethylthio)benzene → HCID 178477269, 화합물

HRID 1491131

반응식

HRID 1491131 반응식
CCSc1ccccc1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.Cc1ccnc(-c2cc(C)ccn2)c1.[Ir].[Ir]>CCSc1cccc(B2OC(C)(C)C(C)(C)O2)c1.CCSc1ccccc1B1OC(C)(C)C(C)(C)O1

참가 물질

7

반응물 1

HCID 12144(Ethylthio)benzene

생성물 2

HCID 1237879692-(2-(Ethylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane수율 24%HCID 178477269HCID 178477269, 화합물수율 30%

시약·촉매·용매 4

HCID 143384,4'-Dimethyl-2,2'-bipyridine시약HCID 2733548Bis(pinacolato)diborane시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 7809P-Xylene용매

반응 조건

온도
55 °C

실험 절차

dtbpy: The mixture of product (110 mg, 83% yield, ortho/meta + para = 0.29); meta- and para- isomers (5b+5bʹ) were obtained by further purification of the crude mixture by GPC (77 mg, 58% yield), colorless oil;

출처 및 근거

ORD 기록
ord-3cf848853d454210a4ad7b64186a1c6e
출처 데이터셋
Borylation dataset from Roche

연결된 노트

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