Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Butyl-5-hydroxymethylimidazole → 2-Butyl-5-formylimidazole
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Butyl-5-hydroxymethylimidazole | HCID 2735673 | — |
| 촉매 | HCID 178418406 | HCID 178418406 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 용매 | 1,4-Dioxane | HCID 31275 | — |
| 생성물 | 2-Butyl-5-formylimidazole | HCID 2735671 | 84.8% |
반응 단계
To a suspension of 2-butyl-1H-imidazole-5-methanol (2.02 g) in dry dichloromethane (40 ml) and dry dioxan (60 ml) was added manganese dioxide (7.05 g). The reaction mixture was heated at reflux for 3.5 h before being filtered, and the filtrate concentrated in vacuo to give the title compound as a white solid (1.69 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05374646 |
| 출처 데이터셋 | uspto-grants-1994_12 |
| ORD ID | ord-6438c970a50e43988334c66cb57dc0f9 |
| 출처 메모 | uspto-grants-1994_12 |