Oxygen → Tcep mpaa

HRID 1501922

반응식

HRID 1501922 반응식
O=O.[CH2:3]([C:16]([OH:18])=[O:17])[CH2:4][P:5]([CH2:11][CH2:12][C:13]([OH:15])=[O:14])[CH2:6][CH2:7][C:8]([OH:10])=[O:9].[SH:19][C:20]1[CH:21]=[C:22]([CH2:26][C:27]([OH:29])=[O:28])[CH:23]=[CH:24][CH:25]=1>P([O-])([O-])([O-])=O>[CH2:7]([C:8]([OH:10])=[O:9])[CH2:6][P:5]([CH2:4][CH2:3][C:16]([OH:18])=[O:17])[CH2:11][CH2:12][C:13]([OH:15])=[O:14].[SH:19][C:20]1[CH:21]=[C:22]([CH2:26][C:27]([OH:29])=[O:28])[CH:23]=[CH:24][CH:25]=1

참가 물질

5

반응물 3

HCID 977OxygenHCID 119411Tris(2-carboxyethyl)phosphineHCID 35431562-(3-Mercaptophenyl)acetic acid

생성물 1

HCID 131734284Tcep mpaa

시약·촉매·용매 1

HCID 1061Phosphate용매

실험 절차

Handling is carried out in a glove box ([O2]<50 ppm). A solution of TCEP at 300 mmol/L is prepared in 0.2 M phosphate buffer at pH=7.2. 3-Mercaptophenylacetic acid (MPAA) (84 mg, 0.5 mmol) is then added. The pH of the TCEP/MPAA solution obtained is adjusted to pH=6.5.

후처리

  1. customHandling is carried out in a glove box

출처 및 근거

ORD 기록
ord-32d60538298644b4ae8105da88788056
출처 데이터셋
uspto-grants-2015_12
특허 번호
US09206224B2

연결된 노트

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