Nonylamine → Nonanenitrile

온도

90 °C

50 g of nonylamine and 50 g of water are introduced into a 750-ml autoclave equipped with a self-aspirating turbine. 5 g of basified Raney nickel doped with 2% by weight of Cr are added. The reactor is flushed with twice 10 bar of nitrogen and then with twice 10 bar of hydrogen. The autoclave is placed under 20 bar of hydrogen, and stirring and heating to 90° C. are carried out. The nonanenitrile resulting from example 5 is then injected using a pump, while keeping the hydrogen pressure constant in the reactor. 350 g of nonanenitrile are injected over the course of 4 h. After the end of the injection, the reaction medium is maintained under the same conditions for 30 min. The temperature is then brought back to 20° C., the reactor is flushed with nitrogen and the catalyst is filtered off. The reaction medium is then distilled under reduced pressure: in this way, the nonylamine is recovered with a yield of 98% (boiling point 201° C. under 760 mmHg).

1. customequipped with a self-aspirating turbine
2. additionare added
3. customThe reactor is flushed with twice 10 bar of nitrogen
4. customare injected over the course of 4 h
5. temperatureAfter the end of the injection, the reaction medium is maintained under the same conditions for 30 min
6. customis then brought back to 20° C.
7. customthe reactor is flushed with nitrogen
8. filtrationthe catalyst is filtered off
9. distillationThe reaction medium is then distilled under reduced pressure
10. customin this way, the nonylamine is recovered with a yield of 98% (boiling point 201° C. under 760 mmHg)

ORD 기록

ord-bd40826d036146b7a82cbf82d53c2d9d

출처 데이터셋

uspto-grants-2015_07

DOI

10.6084/m9.figshare.5104873.v1

특허 번호

US09073822B2