Sodium Hydroxide → Silver(1+) dibenzyl phosphate

HRID 1525135노트

반응식

HRID 1525135 반응식
[P:1]([O-:19])([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:2].[OH-].[Na+].[N+]([O-])([O-])=O.[Ag+:26]>O>[P:1]([O-:19])([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:2].[Ag+:26]

참가 물질

5

반응물 3

HCID 14798Sodium HydroxideHCID 24470Silver NitrateHCID 4193600Dibenzylphosphate

생성물 1

HCID 13248164Silver(1+) dibenzyl phosphate수율 82.6%

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

Dibenzyl phosphate (2.78 g, 10 mmol) in water (40 mL) was cooled in an ice bath. Subsequently, 1N NaOH was added while shaking the flask until the pH of solution was about 7. The solid dissolved almost completely. Then silver nitrate (1.89 g, 11 mmol) in water (20 mL) was added slowly. After adding, the resulting solid was collected by filtration and washed with water. The solid was dried in vacuum over phosphorus pentoxide to yield silver dibenzyl phosphate (3.18 g) (yield, 82.5%) as a white solid.

후처리

  1. dissolutionThe solid dissolved almost completely
  2. additionAfter adding
  3. filtrationthe resulting solid was collected by filtration
  4. washwashed with water
  5. dry with materialThe solid was dried in vacuum over phosphorus pentoxide

출처 및 근거

ORD 기록
ord-3a37b49b2b3f4dc0b9fe1b0ad6857f72
출처 데이터셋
uspto-grants-2015_07
특허 번호
US09079928B2

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