Triphenylphosphine → Triphenyl(10-phenyldecyl)phosphonium bromide

HRID 1525799노트

반응식

HRID 1525799 반응식
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.[C:18]1([P:24]([C:31]2[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=2)[C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>C1(C)C=CC=CC=1>[Br-:1].[C:31]1([P+:24]([C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=2)([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:32]=[CH:33][CH:34]=[CH:35][CH:36]=1

참가 물질

4

반응물 2

HCID 11776Triphenylphosphine2회HCID 27356021-Bromo-10-phenyldecane

생성물 1

HCID 86126936Triphenyl(10-phenyldecyl)phosphonium bromide수율 54.6%

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
100 °C

실험 절차

Compound 11 (7.0 g) was dissolved in toluene (80 mL) and triphenylphosphine (6.8 g) was added thereto, followed by stirring at 100° C. for 12 hours. Triphenylphosphine (1.3 g) was further added, followed by stirring at 100° C. for 24 hours. After cooling the reaction solution to room temperature, the resulting precipitate was washed with toluene three times and the residue was dried under reduced pressure to obtain the title compound (7.2 g) having the following physical property values.

후처리

  1. stirringby stirring at 100° C. for 24 hours
  2. temperatureAfter cooling the reaction solution to room temperature
  3. washthe resulting precipitate was washed with toluene three times
  4. customthe residue was dried under reduced pressure

출처 및 근거

ORD 기록
ord-defc6a76b3924d26a254dcb11cfc59f3
출처 데이터셋
uspto-grants-2015_07
특허 번호
US09085523B2

반응 노트

불러오는 중…