Hydroxycitronellal → 6,10-Dimethylundeca-3-en-2-on-10-ol

HRID 1576599

반응식

HRID 1576599 반응식
[CH3:1][CH:2]([CH2:10][CH:11]=O)[CH2:3][CH2:4][CH2:5][C:6]([OH:9])([CH3:8])[CH3:7]>CC(C)=O>[CH3:1][CH:2]([CH2:3][CH2:4][CH2:5][C:6]([CH3:7])([OH:9])[CH3:8])[CH2:10][CH:11]=[CH:5][C:6](=[O:9])[CH3:7]

참가 물질

3

반응물 1

HCID 7888Hydroxycitronellal

생성물 1

HCID 537842226,10-Dimethylundeca-3-en-2-on-10-ol

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

Ethynylation of 212 g of 6,10-dimethylundeca-3-en-2-on-10-ol obtained by aldol condensation of hydroxycitronellal and acetone was carried out in the same manner as in example 20 except that hydroxycitronellal was used in place of pseudoionone and 269 g of a crude product was thus obtained.

출처 및 근거

ORD 기록
ord-9acb2cf4a40948bba0d43a9326517ce1
출처 데이터셋
uspto-grants-1976_09
특허 번호
US03981930

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