4-(4-Methoxyphenyl)but-3-en-2-one → HCID 12374368, 화합물

HRID 1577040

반응식

HRID 1577040 반응식
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:6][C:7]1[C:15]([CH3:17])([CH3:16])[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[NH+:8]=1.[CH3:18][O:19][C:20]1[CH:25]=[CH:24][C:23]([CH:26]=[CH:27][C:28](=O)[CH3:29])=[CH:22][CH:21]=1>CO>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:29][C:28]1[N+:8]2[C:9]3[C:14]([C:15]([CH3:17])([CH3:16])[C:7]=2[CH:6]=[C:26]([C:23]2[CH:22]=[CH:21][C:20]([O:19][CH3:18])=[CH:25][CH:24]=2)[CH:27]=1)=[CH:13][CH:12]=[CH:11][CH:10]=3

참가 물질

4

반응물 2

HCID 954144-(4-Methoxyphenyl)but-3-en-2-oneHCID 149131883H-Indole, 2,3,3-trimethyl-, perchlorate

생성물 1

HCID 12374368HCID 12374368, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

2,3,3-Trimethyl-3H-indolium perchlorate (5 g.) and 4-p-methoxyphenylbut-3-ene-2-one (10 g.) were heated together on the steam bath for three hours. The cooled mixture was diluted with methanol and filtered. The product was purified by recrystallization from acetonitrile. Yield 4.1 g.; m.p. 298°-300° .

후처리

  1. filtrationfiltered
  2. customThe product was purified by recrystallization from acetonitrile

출처 및 근거

ORD 기록
ord-10a387c8143d4b76b6e143ffaefdfae1
출처 데이터셋
uspto-grants-1976_09
특허 번호
US03983288

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