Hydrochloric Acid → antimony (V) hexyl thioglycolate

HRID 1577066

반응식

HRID 1577066 반응식
[Sb:1](=O)([O-])([O-])[O-].[Na+].[Na+].[Na+].[Sb].[C:10]([O:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:13])[CH2:11][SH:12].Cl>O>[C:10]([O:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:13])[CH2:11][SH:12].[Sb+5:1]

참가 물질

6

반응물 4

HCID 313Hydrochloric AcidHCID 25469Antimonic acid, sodium saltHCID 88471Hexyl mercaptoacetateHCID 5354495Antimony

생성물 1

HCID 86737979antimony (V) hexyl thioglycolate수율 92%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Sodium antimonate obtained from U.S. Antimony Corporation (22.73 g, 0.0563 mole) was placed in the reaction vessel and the hexyl thioglycolate (100 ml, 0.5625 mole) added and stirred. Concentrated hydrochloric acid from Fisher Scientic Co. (9.52 ml, 0.1125 mole) was added dropwise, and an immediate temperature rise of 12° C. occurred. The mixture was thereafter heated and the byproduct of the reaction, water, was distilled over at 96° C. and collected. After 2 hours, a 92% yield of antimony (V) hexyl thioglycolate was obtained. The product was filtered to remove unreacted sodium antimonate and the additional byproduct of the reaction, sodium chloride.

후처리

  1. addition(9.52 ml, 0.1125 mole) was added dropwise
  2. customan immediate temperature rise of 12° C.
  3. temperatureThe mixture was thereafter heated
  4. distillationwas distilled over at 96° C.
  5. customcollected

출처 및 근거

ORD 기록
ord-5d706890fd104c0da660934c84c495f5
출처 데이터셋
uspto-grants-1981_09
특허 번호
US04287118

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