참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | 1-Decanethiol | HCID 8917 | — |
| 반응물 | Antimonic acid, sodium salt | HCID 25469 | — |
| 반응물 | Antimony | HCID 5354495 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | antimony (V) decanethiol | HCID 86737980 | — |
반응 단계
Sodium antimonate obtained from U.S. Antimony Corporation (9.49 g, 0.02347 mole) was placed in a reaction vessel and 1-decanethiol from Eastman Kodak (50 ml, 0.2347 mole) added and stirred. Concentrated hydrochloric acid (3.9 ml, 0.0468 mole) was added dropwise and an immediate temperature increase of 4° C. was observed. The mixture was heated and the byproduct of the reaction, water, was distilled over at 28° C. and a vacuum of 50 mm Hg. After 2.5 hours 45.57 g of antimony (V) decanethiol was obtained. The product was filtered to remove unreacted sodium antimonate and the additional byproduct of the reaction, sodium chloride.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04287118 |
|---|
| 출처 데이터셋 | uspto-grants-1981_09 |
|---|
| ORD ID | ord-c01b6090979e444dbe4c074b43123026 |
|---|
| 출처 메모 | uspto-grants-1981_09 |
|---|
