Hydrochloric Acid → HCID 21503021, 화합물

HRID 1578454노트

반응식

HRID 1578454 반응식
[CH:1]([O:4][C:5]1[CH:13]=[CH:12][CH:11]=[C:10]2[C:6]=1[C:7](=[O:15])[CH2:8][C:9]2=[O:14])([CH3:3])[CH3:2].[N+:16]([O-])([OH:18])=[O:17].Cl>CCOCC>[CH:1]([O:4][C:5]1[CH:13]=[CH:12][CH:11]=[C:10]2[C:6]=1[C:7](=[O:15])[CH:8]([N+:16]([O-:18])=[O:17])[C:9]2=[O:14])([CH3:3])[CH3:2]

참가 물질

5

반응물 3

HCID 313Hydrochloric AcidHCID 944Nitric AcidHCID 21503044HCID 21503044, 화합물

생성물 1

HCID 21503021HCID 21503021, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

4-Isopropyloxy indane-1,3-dione (0.16 g; 0.003 mole) suspended in dry ether (5 ml) was treated dropwise and with stirring with fuming nitric acid (1.0 ml) at 10°C. The resulting dark solution was treated with 5N hydrochloric acid and evaporated to a yellow crystalline product; m.p. (water, hydrochloric acid) 80°-81°C. (Found: C, 57.94; H, 4.43; N, 5.46; C12H11NO5 requires: C, 57.83; H, 4.45; N, 5.62%).

후처리

  1. additionwas treated dropwise
  2. customevaporated to a yellow crystalline product
  3. customm.p. (water, hydrochloric acid) 80°-81°C. (Found: C, 57.94; H, 4.43; N, 5.46; C12H11NO5 requires: C, 57.83; H, 4.45; N, 5.62%)

출처 및 근거

ORD 기록
ord-f9a9aff9923f4fb0a36be665cba5bffd
출처 데이터셋
uspto-grants-1976_02
특허 번호
US03936504

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