Sulfuric Acid → Sodium acetyl sulphate

HRID 1578905노트

반응식

HRID 1578905 반응식
[C:1]([O:4]C(=O)C)(=[O:3])[CH3:2].[S:8]([O-])([O-:11])(=[O:10])=[O:9].[Na+:13].[Na+].S(=O)(=O)(O)O>C(O)(=O)C>[S:8]([O-:11])([O:4][C:1](=[O:3])[CH3:2])(=[O:10])=[O:9].[Na+:13]

참가 물질

5

반응물 3

HCID 1118Sulfuric Acid3회HCID 7918Acetic AnhydrideHCID 24436Sodium Sulfate

생성물 1

HCID 23696766Sodium acetyl sulphate

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

A sulfating mixture comprising sodium acetyl sulfate was prepared as follows: 162.9 grams acetic anhydride and 52.5 grams glacial acetic acid were added to a 1 liter jacketed resin flask. 30.8 grams of sodium sulfate were added and the contents stirred for 5 minutes. 20.15 grams of concentrated sulfuric acid (98% by weight) were added dropwise at such a rate that the temperature of the reactor contents did not exceed 55° C. The rate of addition of sulfuric acid may be increased, if desired, if cooling is applied by circulating ice water through the jacket of the reactor. The reactor was stirred for 30 minutes after the addition of the sulfuric acid was completed.

후처리

  1. customdid not exceed 55° C
  2. temperaturemay be increased
  3. temperatureif cooling
  4. stirringThe reactor was stirred for 30 minutes

출처 및 근거

ORD 기록
ord-e0e27a88685a4b87ba6e0f71f746815a
출처 데이터셋
uspto-grants-1976_02
특허 번호
US03939836

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