2-Chloroaniline → Imidazolidine, 2-(2-chlorophenylimino)-

HRID 1579501

반응식

HRID 1579501 반응식
[Cl:1][C:2]1[CH:8]=[CH:7][CH:6]=[CH:5][C:3]=1[NH2:4].C([N:12]1[CH2:16][CH2:15][NH:14][C:13]1=O)(=O)C>O=P(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:8]=[CH:7][CH:6]=[CH:5][C:3]=1[NH:4][C:13]1[NH:14][CH2:15][CH2:16][N:12]=1

참가 물질

4

반응물 2

HCID 72402-ChloroanilineHCID 79350N-Acetylimidazolidinone

생성물 1

HCID 138342Imidazolidine, 2-(2-chlorophenylimino)-

시약·촉매·용매 1

HCID 24813Phosphorus oxychloride용매

실험 절차

12.75 g of o-chloroaniline and 14.09 g of 1-acetylimidazolidin-2-one in 144 ml of POCl3 are stirred for 71 hours at 60°C. The mixture is worked up as described in Example 19 and 15.45 g, that is to say 65.3%, of the acetyl derivative of 2-(2'-chlorophenylamino)-2-imidazoline are obtained as a crystalline product, which, for analysis, is recrystallised from i-propanol and toluene. Melting point: 142°-143°C

출처 및 근거

ORD 기록
ord-3da06787c09344e7a36d5afe55ddb66f
출처 데이터셋
uspto-grants-1976_01
특허 번호
US03931216

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