Toluene → HCID 178506898, 화합물

HRID 1580392

반응식

HRID 1580392 반응식
I/[CH:2]=[CH:3]/[CH:4]([O:10][C:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].C1(C)C=CC=CC=1.C([Li:41])CCC>CCCCCC>[C:12]1([C:11]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[O:10][CH:4]([CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])/[CH:3]=[CH:2]/[Li:41])[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

참가 물질

5

반응물 3

HCID 1140TolueneHCID 201446361-Iodo-3-triphenylmethoxy-trans-1-octeneHCID 178418339Butyllithium

생성물 1

HCID 178506898HCID 178506898, 화합물

시약·촉매·용매 1

HCID 8058Hexane용매

반응 조건

온도
-40 °C

실험 절차

To a solution of 4.96 g. of 1-iodo-3-triphenylmethoxy-trans-1-octene (Example 730) in 10 ml. of toluene cooled to -78°C. is added under an inert atmosphere 1 molar equivalent of n-butyllithium dissolved in hexane. The reaction mixture is allowed to warm to -40°C. and is then maintained at that temperature for 1hour to yield a hydrocarbon solution of 3-triphenylmethoxy-trans-1-octenyllithium.

후처리

  1. temperatureis then maintained at that temperature for 1hour

출처 및 근거

ORD 기록
ord-8707e8110a13498db0df5a106c014b3e
출처 데이터셋
uspto-grants-1976_01
특허 번호
US03932479

연결된 노트

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