홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

p-Toluenesulfonic acid → HCID 70100107, 화합물

HRID 1581907
노트
인쇄 미리보기

반응식

HRID 1581907 반응식
[CH:1]([O:3][CH2:4][CH:5]([CH3:7])[CH3:6])=[CH2:2].[C:8]1([CH3:18])[CH:13]=[CH:12]C(S(O)(=O)=O)=[CH:10][CH:9]=1.C(N([CH2:24][CH3:25])CC)C.[C:26]([O:29][CH2:30][CH3:31])(=[O:28])C>C(OC(C)COCC)(=O)C>[CH2:4]([O:3][CH:1]([O:29][C:30]1[CH:31]=[CH:18][C:8]([CH:13]=[CH2:12])=[CH:9][CH:10]=1)[CH3:2])[CH:5]([CH3:7])[CH3:6].[OH:29][C:30]1[CH:31]=[CH:18][C:8]([CH:13]=[CH2:12])=[CH:9][CH:10]=1.[C:26]([O:29][C:8]([CH3:9])([CH3:13])[CH3:18])(=[O:28])[CH:24]=[CH2:25]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 6101p-Toluenesulfonic acidHCID 7992Vinyl isobutyl etherHCID 8471TriethylamineHCID 8857Ethyl Acetate

생성물 1

HCID 70100107HCID 70100107, 화합물

시약·촉매·용매 1

HCID 1713782-Propanol, 1-ethoxy-, 2-acetate용매2회

반응 조건

온도
60 °C

실험 절차

The above polymer (A-48) (20 g) was dissolved in 80 g of propylene glycol monoethyl ether acetate (PGMEA) and the solution was heated at 60° C., and then the pressure was gradually reduced until 20 mmHg, thereby PGMEA and the moisture in the reaction system were azeotropically hydrated. After the azeotropic hydration, the temperature was lowered to 20° C., 2.2 g of isobutyl vinyl ether was added thereto, and further 3 mg of p-toluenesulfonic acid was added. After the addition, reaction was performed for 2 hours, and a small amount of triethylamine was added to neutralize the acid. Thereafter, ethyl acetate was added to the reaction solution, and the salt was removed by washing with ion exchange water. Further, ethyl acetate and water were distilled off under reduced pressure, thereby polymer A-16 was obtained.

후처리

  1. customwas lowered to 20° C.
  2. additionAfter the addition, reaction
  3. customthe salt was removed
  4. washby washing with ion exchange water
  5. distillationFurther, ethyl acetate and water were distilled off under reduced pressure
  6. customwas obtained

출처 및 근거

ORD 기록
ord-ad5e0c7567b14f32bf459e74aca1bf7e
출처 데이터셋
uspto-grants-2004_05
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06733951B2

반응 노트

불러오는 중…

이 페이지에서참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트