Hexadiene → HCID 22717334, 화합물

HRID 1583090노트

반응식

[CH2:1]=[CH:2][CH:3]=[CH:4][CH2:5][CH3:6].[Cl:7][SiH:8]([Cl:10])[Cl:9].[I-].C([P+](CCCC)(CCCC)CCCC)CCC>>[CH3:1][CH:2]1[Si:8]([Cl:9])([Cl:7])[CH:5]([CH3:6])[CH:4]=[CH:3]1.[Cl:7][Si:8]([Cl:10])([Cl:9])[CH:2]([CH:3]=[CH:4][CH:5]([Si:8]([Cl:10])([Cl:9])[Cl:7])[CH3:6])[CH3:1]

참가 물질

반응물 3

HCID 11602Hexadiene

HCID 24811Trichlorosilane

HCID 201022Phosphonium, tetrabutyl-, iodide (1:1)

생성물 2

HCID 22717334HCID 22717334, 화합물수율 60%

HCID 73993291HCID 73993291, 화합물수율 10%

반응 조건

온도: 180 °C

실험 절차

As in Example 1, 1,3-hexadiene (0.99 g, 12.06 mmol), trichlorosilane (6.60 g, 48.73 mmol) and tetrabutylphosphonium iodide (0.47 g, 1.22 mmol) were added in a 25 mL stainless steel tube under nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 180 ° C. for 10 hours. The resulting mixture was distilled to yield 1.32 g (yield: 60%) of 1,1-dichloro-2,5-dimethyl-silacyclo-3-pentene and 0.43 g (yield: 10%) of 2,5-bis(trichlorosilyl)-3-hexene main products.

후처리

distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록: ord-eb369b450fbe40849e01424635a5d226
출처 데이터셋: uspto-grants-2004_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06740766B2

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