1,3-Cycloheptadiene → 2,6-Bis(trichlorosilyl)-1-heptene

HRID 1583094노트

반응식

HRID 1583094 반응식
[CH:1]1[CH2:7][CH2:6][CH2:5][CH:4]=[CH:3][CH:2]=1.[Cl:8][SiH:9]([Cl:11])[Cl:10]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[Cl:8][Si:9]([Cl:11])([Cl:10])[C:2]([CH2:3][CH2:4][CH2:5][CH:6]([Si:9]([Cl:11])([Cl:10])[Cl:8])[CH3:7])=[CH2:1]

참가 물질

4

반응물 2

HCID 199691,3-CycloheptadieneHCID 24811Trichlorosilane

생성물 1

HCID 227173252,6-Bis(trichlorosilyl)-1-heptene수율 25%

시약·촉매·용매 1

HCID 75311Tetrabutylphosphonium chloride촉매

반응 조건

온도
180 °C

실험 절차

As in Example 1, 1,3-cycloheptadiene (1.00 g, 10.62 mmol), trichlorosilane (5.76 g, 42.52 mmol) and tetrabutylphosphonium chloride (0.31 g, 1.05 mmol) were added in a 25 mL stainless steel tube under nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 180° C. for 18 hours. The resulting mixture was distilled to yield 0.96 g (yield: 25%) of 2,6-bis(trichlorosilyl)-1-heptene.

후처리

  1. distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록
ord-8853b7a278fa4438a4c4b456d65f9038
출처 데이터셋
uspto-grants-2004_05
특허 번호
US06740766B2

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