3,4-diphenyl-5H-furan-2-one → 3,4-Diphenyl-1,5-dihydro-pyrrol-2-on

반응식

[C:1]1([C:7]2[C:8](=O)[O:9][CH2:10][C:11]=2[C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([O-])(=O)C.[NH4+:23]>>[C:1]1([C:7]2[C:8](=[O:9])[NH:23][CH2:10][C:11]=2[C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

반응물 2

HCID 3440493,4-diphenyl-5H-furan-2-one

HCID 517165Ammonium Acetate

생성물 1

HCID 123065323,4-Diphenyl-1,5-dihydro-pyrrol-2-on

실험 절차

Analogous to the reaction of 3,4-diphenyl-2(5H)-furanone with ammonium acetate, forming 3,4-diphenyl-1,5-dihydro-pyrrol-2-on in Rio, G. and Sekiz, B. (see above):

출처 및 근거

ORD 기록: ord-03140703b20a4ce9ac3bc2266f7ee065
출처 데이터셋: uspto-grants-1999_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05939415

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