Allyl Mercaptan → HCID 9794857, 화합물

HRID 1585994노트

반응식

HRID 1585994 반응식
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:8][C:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[C:12](Cl)=[N:11][N:10]=1)[CH3:7]>CO>[CH2:6]([O:8][C:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[C:12]([S:5][CH2:2][CH:3]=[CH2:4])=[N:11][N:10]=1)[CH3:7]

참가 물질

5

반응물 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 212176601-Chloro-4-ethoxyphthalazine

생성물 1

HCID 9794857HCID 9794857, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

0.23 g(0.01 mol) of metallic sodium was dissolved in 100 ml of absolute methanol and then mixed with 0.93 ml(0.01 mol) of allylmercaptan. To this mixture was added 2.09 g(0.01 mol) of 1-ethoxy-4-chlorophthalazine obtained from Preparation 10. The reaction solution was refluxed for 3 hours and then treated according to the same manner as Example 1 to obtain the title compound as a freezing white crystal.

후처리

  1. customobtained from Preparation 10
  2. temperatureThe reaction solution was refluxed for 3 hours
  3. additiontreated

출처 및 근거

ORD 기록
ord-410766fcd3fc46009dbb63f29386785c
출처 데이터셋
uspto-grants-1999_08
특허 번호
US05942511

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