m-Chloroperbenzoic acid → 4-(diethylphosphonomethyl)pyridine-N-oxide
반응식
[CH2:1]([O:3][P:4]([CH2:9][C:10]1[CH:15]=[CH:14][N:13]=[CH:12][CH:11]=1)([O:6][CH2:7][CH3:8])=[O:5])[CH3:2].ClC1C=CC=C(C(OO)=[O:24])C=1>C(Cl)(Cl)Cl>[CH2:1]([O:3][P:4]([CH2:9][C:10]1[CH:11]=[CH:12][N+:13]([O-:24])=[CH:14][CH:15]=1)([O:6][CH2:7][CH3:8])=[O:5])[CH3:2]참가 물질
4
실험 절차
A mixture of 2.2 g of 4-(diethylphosphonomethyl)pyridine [Roczniki Chem. 38, (4), 625 (1964); Chem. Abst. 61, 10703], 2.2 g of m-chloroperbenzoic acid and 30 ml of chloroform is stirred at room temperature for 16 hours. The solvent is removed in vacuo and water is added. After washing the aqueous layer with ether, the water is removed in vacuo to afford 4-(diethylphosphonomethyl)pyridine-N-oxide.
후처리
- customThe solvent is removed in vacuo and water
- additionis added
- washAfter washing the aqueous layer with ether
- customthe water is removed in vacuo
출처 및 근거
- ORD 기록
- ord-6cd02ad64dd7472c9d698b8ecb45cca2
- 출처 데이터셋
- uspto-grants-1993_06
- 특허 번호
- US05217963
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