Dibromomethane → Methylidenecyclotridecane

HRID 1589155노트

반응식

HRID 1589155 반응식
[CH:1]1([CH:14]=O)[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.BrCBr.C1(=O)CCCCCCCCCCCC1>[Ti](Cl)(Cl)(Cl)Cl.[Zn].O1CCCC1>[CH2:14]=[C:1]1[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]1

참가 물질

7

반응물 3

HCID 3024DibromomethaneHCID 79114CyclotridecanoneHCID 20247944Cyclotridecanecarbaldehyde

생성물 1

HCID 13867802Methylidenecyclotridecane

시약·촉매·용매 3

HCID 23994Zinc촉매HCID 24193Titanium Tetrachloride촉매HCID 8028Tetrahydrofuran용매

실험 절차

The cyclotridecanecarbaldehyde listed above is also a novel compound which is prepared in the following manner: Titanium tetrachloride is added to a mixture of zinc dust, anhydrous tetrahydrofuran and dibromomethane. To the resulting mixture is added cyclotridecanone to yield methylene cyclotridecane which is then epoxidized with m-chloroperbenzoic acid. After purification, the epoxidized product is reacted with boron trifluoride-ether complex in anhydrous dichloromethane to yield cyclotridecanecarbaldehyde.

후처리

  1. customis prepared in the following manner

출처 및 근거

ORD 기록
ord-d4299876a4694bef9e6e660807ed5027
출처 데이터셋
uspto-grants-1986_02
특허 번호
US04568490

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