Benzene → 2-Decanone

HRID 1589289

반응식

HRID 1589289 반응식
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].C1C=CC=CC=1.[OH2:17]>[Cl-].C([N+](C)(C)C)CCCCCCCCCCC.O.O.[Cu](Cl)Cl.[Pd](Cl)Cl>[CH3:1][C:2](=[O:17])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH3:1][CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

참가 물질

8

반응물 3

HCID 241BenzeneHCID 962WaterHCID 133811-Decene

생성물 2

HCID 127412-DecanoneHCID 32899trans-2-Decene

시약·촉매·용매 3

HCID 8152Dodecyltrimethylammonium chloride촉매HCID 24290Palladium Chloride촉매HCID 61482Cupric chloride dihydrate촉매

실험 절차

A mixture of copper (II) chloride dihydrate [10 mmol] and palladium (II) chloride [1.0 mmol] in water [10 ml] was stirred for 10 minutes at room temperature. Then 1-decene [3.51 g, 25 mmol] was added followed by benzene [15 ml] and dodecyltrimethylammonium chloride [2.0 mmol]. Oxygen was bubbled through the solution at 80° C. for 48 hours. After cooling to room temperature, ethyl acetate (15 ml) was added and the solution was filtered. The filtrate was dried using anhydrous magnesium sulphate, and then distilled to provide pure 2-decanone in 75% yield and 2-decene in 2% yield.

후처리

  1. customOxygen was bubbled through the solution at 80° C. for 48 hours
  2. temperatureAfter cooling to room temperature
  3. additionethyl acetate (15 ml) was added
  4. filtrationthe solution was filtered
  5. customThe filtrate was dried
  6. distillationdistilled

출처 및 근거

ORD 기록
ord-7ba009f9c7a14492b560de5cbc51e7a1
출처 데이터셋
uspto-grants-1986_02
특허 번호
US04568770

연결된 노트

불러오는 중…