1-Decene → Methyltridecylsilane

HRID 1589606

반응식

HRID 1589606 반응식
C[SiH:2]([CH2:13]CCCCCCCCC)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[CH2:23]=[CH:24][CH2:25]CCCCCCC>C1C=CC=CC=1.[C-]#[O+].C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Rh]>[CH3:13][SiH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:23][CH2:24][CH3:25]

참가 물질

5

반응물 2

HCID 133811-DeceneHCID 71366123Methyldidecylsilane

생성물 1

HCID 123907608Methyltridecylsilane수율 85%

시약·촉매·용매 2

HCID 10941995Carbonylhydridotris(triphenylphosphine)rhodium(I)촉매HCID 241Benzene용매

실험 절차

A mixture of 1.53 grams of methyldidecylsilane, and 0.70 gram of 1-decene in 5 milliliters of benzene was reacted for 25 hours at 50° C. in the presence of 0.005 gram hydridocarbonyltris(triphenylphosphine)rhodium(I). Chromatographic analysis showed that an 85 percent yield of methyltridecylsilane was formed at a 65 percent silane conversion.

출처 및 근거

ORD 기록
ord-41f29fe13006406dbcfb4c156e765557
출처 데이터셋
uspto-grants-1986_02
특허 번호
US04572791

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