참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methyl Acrylate | HCID 7294 | — |
| 반응물 | Tetrahydrofuran | HCID 8028 | — |
| 반응물 | Piperidine | HCID 8082 | — |
| 반응물 | 2,5-Dimethyl-2,5-dihydroxy-1,4-dithiane | HCID 62105 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Methyl 3-acetonylmercaptopropionate | HCID 15030534 | — |
반응 단계
90.1 g (0.5 mol) of 2,5-dihydroxy-2,5-dimethyl-1,4-dithiane are initially introduced into 100 ml of absolute tetrahydrofuran. 1.0 g of piperidine is then added, and 94.7 g (0.945 mol) of methyl acrylate are added dropwise at 10°-15° C, during which process another two portions of 0.5 g of piperidine are added at the same time. The mixture is subsequently stirred for 60 minutes at 60° C. It is allowed to cool and introduced into 500 ml of water.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05201936 |
|---|
| 출처 데이터셋 | uspto-grants-1993_04 |
|---|
| ORD ID | ord-d63fb943fd6245dab14c117df0577849 |
|---|
| 출처 메모 | uspto-grants-1993_04 |
|---|
