Azobisisobutyronitrile → HCID 86746742, 화합물

HRID 1590762노트

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HRID 1590762 반응식
[CH:1]([O:3][CH2:4][CH2:5][C:6]#[N:7])=[CH2:2].[C:8]([O:12][CH2:13][CH2:14][C:15]#[N:16])(=[O:11])[CH:9]=[CH2:10].N(C(C)(C)C#N)=NC(C)(C)C#N>CC(C)=O>[CH:1]([O:3][CH2:4][CH2:5][C:6]#[N:7])=[CH2:2].[C:8]([O:12][CH2:13][CH2:14][C:15]#[N:16])(=[O:11])[CH:9]=[CH2:10]

참가 물질

5

반응물 3

HCID 6547AzobisisobutyronitrileHCID 78252-Cyanoethyl acrylateHCID 11400730Propanenitrile, 3-(ethenyloxy)-

생성물 1

HCID 86746742HCID 86746742, 화합물수율 90%

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

A nitrogen line was connected to a two-necked flask (100 ml) provided with a cooling tube so that the air in the flask was replaced with nitrogen gas. 0.02 mole of cyanoethyl vinyl ether, which was distilled at least twice, 0.02 mole of cyanoethyl acrylate, 20 ml of acetone and 2,2'-azobisisobutyronitrile in an amount of 2mol% relative to the total amount of the monomers were then placed in the flask, followed by polymerization at 50° C. for 24 hours. The thus-formed copolymer was then reprecipitated by using methanol to obtain 4 g of an intended cyanoethyl vinyl ether-cyanoethyl acrylate copolymer. The composition ratio (cyanoethyl vinyl ether:cyanoethyl acrylate) of the copolymer was 2:3.

후처리

  1. customA nitrogen line was connected to a two-necked flask
  2. custom(100 ml) provided with a cooling tube so that the air in the flask
  3. customfollowed by polymerization at 50° C. for 24 hours
  4. customThe thus-formed copolymer was then reprecipitated

출처 및 근거

ORD 기록
ord-d7a4bee3dddb4e57bb84ebcdcfc72c52
출처 데이터셋
uspto-grants-1993_04
특허 번호
US05204428

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