4-Methoxybenzenethiol → Ethyl octanoate

HRID 1595578

반응식

HRID 1595578 반응식
[CH2:1]([O:3][C:4](=[O:13])[CH:5](Br)[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH3:2].COC1C=CC(S)=CC=1.C(OC(=O)C(SC1C=CC(OC)=CC=1)CCCCCC)C>>[CH2:1]([O:3][C:4](=[O:13])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH3:2]

참가 물질

4

반응물 3

HCID 127654-MethoxybenzenethiolHCID 95580Ethyl 2-bromooctanoateHCID 114383212-(4-Methoxy-phenylsulfanyl)-octanoic acid ethyl ester

생성물 1

HCID 7799Ethyl octanoate

실험 절차

2-4-Methoxy-phenylsulfanyl)-octanoic acid ethyl ester was prepared according to the general method as outlined in example 9. Starting from ethyl-2-bromooctanoate (11.8 g, 47.3 mmol) and 4-methoxythiophenol (6 g, 43 mmol). Yield: 7.24 g (57%); clear oil; MS: 311.2 (M+H)+, 2-4-Methoxy-benzenesulfonyl)-octanoic acid ethyl ester was prepared according to the general method as outlined in example 9. Starting from 2-(4-methoxy-phenylsulfanyl)-octanoic acid ethyl ester (4.0 g, 13.6 mmol). Yield 3.7 g (83%); clear oil; MS: 343.3 (M+H)+.

후처리

  1. custom2-4-Methoxy-phenylsulfanyl)-octanoic acid ethyl ester was prepared

출처 및 근거

ORD 기록
ord-dcd8fdfeaa8a41c2acdbf939d5c94c6b
출처 데이터셋
uspto-grants-2001_09
특허 번호
US06288086B1

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