Oxygen → Hydroperoxide, phenylmethyl

반응식

[O:1]=[O:2].[C:3]1([CH3:9])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>>[CH2:9]([O:1][OH:2])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

반응물 2

HCID 977Oxygen

HCID 1140Toluene2회

생성물 1

HCID 6451509Hydroperoxide, phenylmethyl

실험 절차

750 G of toluene are introduced into a 1.5 liter stainless steel autoclave which is shaken; the toluene is oxidised, at 180°C under a pressure of 20 bars, with air depleted of oxygen until it contains only 8%, with an hourly flow rate of 240 liters (measured under normal temperature and pressure). After 1 hour 30 minutes the reaction mixture is cooled. The hydroperoxide is then purified via its sodium salt. 11.4 G of benzyl hydroperoxide, containing 85% by weight of pure product, are thus obtained.

후처리

customis oxidised, at 180°C under a pressure of 20 bars, with air
temperatureAfter 1 hour 30 minutes the reaction mixture is cooled
customThe hydroperoxide is then purified via its sodium salt
addition11.4 G of benzyl hydroperoxide, containing 85% by weight of pure product
customare thus obtained

출처 및 근거

ORD 기록: ord-8d465e630e6645a18cda1fa38fb4bfbb
출처 데이터셋: uspto-grants-1976_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03948995

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