Allyl Alcohol → (3-Allyl-)heptafluorobutan-2-one

HRID 1609146

반응식

HRID 1609146 반응식
[F:1][C:2]([F:12])([F:11])[C:3]([F:10])=[C:4](F)[C:5]([F:8])([F:7])[F:6].[CH2:13](O)[CH:14]=[CH2:15].[OH-:17].[K+]>O>[CH2:15]([C:3]([F:10])([C:2]([F:1])([F:11])[F:12])[C:4](=[O:17])[C:5]([F:6])([F:7])[F:8])[CH:14]=[CH2:13]

참가 물질

5

반응물 3

HCID 7858Allyl AlcoholHCID 96781,1,1,2,3,4,4,4-Octafluorobut-2-eneHCID 14797Potassium Hydroxide

생성물 1

HCID 22074693(3-Allyl-)heptafluorobutan-2-one

시약·촉매·용매 1

HCID 962Water용매

실험 절차

396 g (1.98 mol) of octafluorobut-2-ene is condensed into 116 g (2 mol) of allyl alcohol at -5° C. Then 113 g (1.98 mol) of KOH, dissolved in 150 ml of water, is slowly added dropwise over the course of 3 hours, the temperature being maintained at 0°-5° C. Stirring continues overnight at room temperature and working-up is performed in the same way as in Example 2a.

후처리

  1. additionis slowly added dropwise over the course of 3 hours
  2. temperaturethe temperature being maintained at 0°-5° C

출처 및 근거

ORD 기록
ord-5344c9fec59d4d58975ffa741fb2bfb6
출처 데이터셋
uspto-grants-1995_03
특허 번호
US05399645

연결된 노트

불러오는 중…