Methacrylic Acid → 1-(11-Methacryloyloxyundecyl)-hydroquinone
반응식
[C:1]1(=[O:8])[CH:6]=[CH:5][C:4](=[O:7])[CH:3]=[CH:2]1.[C:9](OC)(=O)[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH:18]=[CH2:19].B#B.[H-].[Al+3].[Li+].[H-].[H-].[H-].[C:31]([OH:36])(=[O:35])[C:32]([CH3:34])=[CH2:33]>>[C:31]([O:36][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][C:4]1([CH:5]=[CH:6][C:1]([OH:8])=[CH:2][CH2:3]1)[OH:7])(=[O:35])[C:32]([CH3:34])=[CH2:33]참가 물질
6
실험 절차
2-(11-Hydroxyundecyl)-hydroquinone obtained from 2-(10-carboxydecyl)-hydroquinone (prepared from p-benzo-quinone and methyl undec-10-enoate by using diborane and then carrying out hydrolysis) by reduction with lithium aluminium hydride is esterified with methacrylic acid to give 1-(11-methacryloyloxyundecyl)-hydroquinone.