2,7-Naphthalenediol → 2,7-Bis(propargyloxycarbonyloxy)naphthalene

HRID 1614020

반응식

HRID 1614020 반응식
[OH:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][C:6]([OH:12])=[CH:7][CH:8]=2)[CH:3]=1.Cl[C:14]([O:16][CH2:17][C:18]#[CH:19])=[O:15]>>[CH2:17]([O:16][C:14]([O:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][C:6]([O:12][C:14]([O:16][CH2:17][C:18]#[CH:19])=[O:15])=[CH:7][CH:8]=2)[CH:3]=1)=[O:15])[C:18]#[CH:19]

참가 물질

3

반응물 2

HCID 113972,7-NaphthalenediolHCID 3356829Propargyl chloroformate

생성물 1

HCID 197860132,7-Bis(propargyloxycarbonyloxy)naphthalene수율 83.6%

실험 절차

Analogous to Example 19, 2,7-dihydroxynaphthalene was reacted with propargyl chloroformate to produce the title compound. Yield was 83.6% theory. m.p. 94°-96° C.

출처 및 근거

ORD 기록
ord-0ba9c05220ca4bababfcdae17afa5c67
출처 데이터셋
uspto-grants-1993_03
특허 번호
US05194653

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