Glycidyl methacrylate → 1-Ethoxy-2-(2-methoxyethoxy)ethane

HRID 1618841

반응식

HRID 1618841 반응식
[C:1]([O:6][CH2:7][CH:8]1[O:10][CH2:9]1)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:11]([O:16][CH:17]([O:19][CH2:20][CH3:21])[CH3:18])(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:22]([O:27][CH2:28][CH2:29][OH:30])(=[O:26])[C:23]([CH3:25])=[CH2:24].[C:31]([O:36][CH2:37][C:38]1[CH:43]=[CH:42][CH:41]=[CH:40][CH:39]=1)(=[O:35])[C:32]([CH3:34])=[CH2:33].N(C(C)(CC)C([O-])=O)=NC(C)(CC)C([O-])=O>CCCCCCC.C(C(C)=O)C(C)C>[CH3:1][O:6][CH2:7][CH2:8][O:10][CH2:21][CH2:20][O:19][CH2:17][CH3:18].[C:1]([O:6][CH2:7][CH:8]1[O:10][CH2:9]1)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:11]([O:16][CH:17]([O:19][CH2:20][CH3:21])[CH3:18])(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:22]([O:27][CH2:28][CH2:29][OH:30])(=[O:26])[C:23]([CH3:25])=[CH2:24].[C:31]([O:36][CH2:37][C:38]1[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=1)(=[O:35])[C:32]([CH3:34])=[CH2:33]

참가 물질

9

반응물 5

HCID 7837Glycidyl methacrylateHCID 133602-Hydroxyethyl MethacrylateHCID 17236Benzyl methacrylateHCID 201933451-Ethoxyethyl Methacrylate (stabilized with MEHQ)HCID 219175032,2'-Azobis(methyl 2-methylpropanate)

생성물 2

HCID 138471-Ethoxy-2-(2-methoxyethoxy)ethaneHCID 86655549Glycidyl methacrylate 1-ethoxyethyl methacrylate 2-hydroxyethyl methacrylate benzyl methacrylate

시약·촉매·용매 2

HCID 7909Methyl Isobutyl Ketone용매HCID 8900Heptane용매

실험 절차

A 500 ml three-necked flask was charged with 34.1 g (0.24 mol) of glycidyl methacrylate, 28.5 g (0.18 mol) of 1-ethoxyethyl methacrylate, 7.8 g (0.06 mol) of 2-hydroxyethyl methacrylate, 21.1 g (0.12 mol) of benzyl methacrylate and 300 ml of methyl isobutyl ketone. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) as a radical polymerization initiator was added to the mixture, and polymerization was performed in a nitrogen stream at 80° C. for six hours. The obtained reaction liquid was cooled, and poured in a large volume of heptane, thereby precipitating a polymer. The polymer crystal was collected by filtration, and dissolved in diethylene glycol ethyl methyl ether. The heptane and methyl isobutyl ketone contained in the solution were distilled off in vacuum, thereby obtaining a diethylene glycol ethyl methyl ether solution of polymer A2-6 (glycidyl methacrylate/1-ethoxyethyl methacrylate/2-hydroxyethyl methacrylate/benzyl methacrylate).

후처리

  1. customThe obtained reaction liquid
  2. temperaturewas cooled
  3. customprecipitating a polymer
  4. filtrationThe polymer crystal was collected by filtration
  5. dissolutiondissolved in diethylene glycol ethyl methyl ether
  6. distillationwere distilled off in vacuum

출처 및 근거

ORD 기록
ord-c473767bd469474d919b7b34f014aece
출처 데이터셋
uspto-grants-2014_07
특허 번호
US08771907B2

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