Aniline → N-(3-Methoxybenzylidene)aniline

HRID 1632608

반응식

HRID 1632608 반응식
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[CH:9][CH:10]=1)[CH:6]=O.[NH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>CCOCC>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[CH:9][CH:10]=1)[CH:6]=[N:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

참가 물질

4

반응물 2

HCID 6115AnilineHCID 115693-Methoxybenzaldehyde

생성물 1

HCID 555084N-(3-Methoxybenzylidene)aniline

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

A solution of 85.4 gm. of 3-methoxybenzaldehyde, 58.7 gm. of aniline, and 185 gm. of 3A molecular sieves in 700 ml. of anhydrous ether was refluxed for 16 hours. The ether was dried (Na2SO4), filtered, and concentrated in vacuo to an oil which upon distillation provided 93.2 gm of oil. b.p. 141°-143°/0.5 Torr.

후처리

  1. dry with materialThe ether was dried (Na2SO4)
  2. filtrationfiltered
  3. concentrationconcentrated in vacuo to an oil which upon distillation

출처 및 근거

ORD 기록
ord-312d2c2fdff149489cd828aa97a97e7e
출처 데이터셋
uspto-grants-1984_10
특허 번호
US04476311

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