N,N-di-n-Butyl-2-benzyloxyacetamide → N,N-di-n-Butyl-2-hydroxyacetamide

HRID 1635077

반응식

HRID 1635077 반응식
[CH2:1]([N:5]([CH2:17][CH2:18][CH2:19][CH3:20])[C:6](=[O:16])[CH2:7][O:8]CC1C=CC=CC=1)[CH2:2][CH2:3][CH3:4]>C(O)C.[Pd].[C]>[CH2:1]([N:5]([CH2:17][CH2:18][CH2:19][CH3:20])[C:6](=[O:16])[CH2:7][OH:8])[CH2:2][CH2:3][CH3:4]

참가 물질

4

반응물 1

HCID 18675619N,N-di-n-Butyl-2-benzyloxyacetamide

생성물 1

HCID 11008655N,N-di-n-Butyl-2-hydroxyacetamide수율 111.1%

시약·촉매·용매 2

HCID 178418390HCID 178418390, 화합물촉매HCID 702Ethanol용매

실험 절차

4 g of N,N-di-n-butyl-2-benzyloxyacetamide were dissolved in 50 ml of ethanol, and a spatula tip of Pd/carbon was added. The mixture was stirred under a hydrogen atmosphere for 16 hours, and then the catalyst was filtered off and the solvent was distilled off. 3 g of an oil were isolated and were immediately reacted further.

후처리

  1. filtrationthe catalyst was filtered off
  2. distillationthe solvent was distilled off

출처 및 근거

ORD 기록
ord-a9fb9dcbd46a4b5199a190bd6340d452
출처 데이터셋
uspto-grants-2003_01
특허 번호
US06509341B1

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