Hydrochloric Acid → p-1-Ethoxyethoxystyrene p-hydroxystyrene p-tert-butoxystyrene

HRID 1636200

반응식

HRID 1636200 반응식
Cl.[OH:2][C:3]1[CH:10]=[CH:9][C:6]([CH:7]=[CH2:8])=[CH:5][CH:4]=1.[C:11]([O:15][C:16]1C=CC(C=C)=C[CH:17]=1)(C)(C)[CH3:12].[OH:24][C:25]1[CH:32]=[CH:31][C:28]([CH:29]=[CH2:30])=[CH:27][CH:26]=1.[C:33]([O:37][C:38]1[CH:45]=[CH:44][C:41]([CH:42]=[CH2:43])=[CH:40][CH:39]=1)([CH3:36])([CH3:35])[CH3:34]>C(O)(C)C.O>[CH2:11]([O:15][CH2:16][CH2:17][O:2][C:3]1[CH:10]=[CH:9][C:6]([CH:7]=[CH2:8])=[CH:5][CH:4]=1)[CH3:12].[OH:24][C:25]1[CH:32]=[CH:31][C:28]([CH:29]=[CH2:30])=[CH:27][CH:26]=1.[C:33]([O:37][C:38]1[CH:39]=[CH:40][C:41]([CH:42]=[CH2:43])=[CH:44][CH:45]=1)([CH3:36])([CH3:34])[CH3:35]

참가 물질

7

반응물 4

HCID 313Hydrochloric AcidHCID 624534-VinylphenolHCID 5775311-(Tert-butoxy)-4-ethenylbenzeneHCID 68598693p-Hydroxystyrene p-tert-butoxystyrene

생성물 1

HCID 131721427p-1-Ethoxyethoxystyrene p-hydroxystyrene p-tert-butoxystyrene

시약·촉매·용매 2

HCID 962Water용매HCID 3776Isopropanol용매

실험 절차

Poly(p-tert-butoxystyrene) obtained in the same manner as described in Production Example 1(1) in an amount of 15.0 g was suspended in isopropanol and added with 15 ml of concentrated hydrochloric acid. The reaction was carried out at 70° to 80° C. for 4 hours with stirring. After cooling, the reaction solution was poured into 1000 ml of water to deposit crystals. The deposited crystals were filtered, washed with water and dried under reduced pressure to give 9.4 g of white powdered crystals of poly(p-hydroxystyrene/p-tert-butoxystyrene). The proportion of the p-hydroxystyrene unit and the p-tert-butoxystyrene unit of the obtained polymer was about 30:64:6 measured by 1H NMR. Mw was about 17,500 and the degree of dispersion was 1.16 (GPC method, polystyrene standard).

후처리

  1. temperatureAfter cooling
  2. filtrationThe deposited crystals were filtered
  3. washwashed with water
  4. customdried under reduced pressure
  5. customto give 9.4 g

출처 및 근거

ORD 기록
ord-cb49ff37dc9b429a91025d15adc62fb4
출처 데이터셋
uspto-grants-2000_03
특허 번호
US06033826

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