Benzyl Chloride → Dibenzyl sulfide

HRID 1638766

반응식

HRID 1638766 반응식
O.O.O.O.O.O.O.O.O.[S-2:10].[Na+].[Na+].[CH2:13](Cl)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>O>[CH2:13]([S:10][CH2:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

참가 물질

4

반응물 2

HCID 7503Benzyl ChlorideHCID 73972Sodium sulfide nonahydrate

생성물 1

HCID 10867Dibenzyl sulfide수율 188.5%

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

Sodium sulphide nonahydrate (2.40 g, 0.01 mol), benzyl chloride (1.26 g, 0.01 mol), water (3 ml) and compound 1 (0.5 mmol) were stirred at 70°-78° C. for 20 minutes. The reaction mixture was poured into water and left overnight at room temperature. The white crystals thus obtained were filtered off and dried to give 2.02 g of benzyl sulphide.

후처리

  1. customThe white crystals thus obtained
  2. filtrationwere filtered off
  3. customdried

출처 및 근거

ORD 기록
ord-1d2a958485814bccb29f50f62fb0ee9c
출처 데이터셋
uspto-grants-1989_11
특허 번호
US04880894

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