1-(Hexyloxy)-2-nitrobenzene → 2-(Hexyloxy)aniline

HRID 1639114노트

반응식

HRID 1639114 반응식
[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[N+:14]([O-])=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[H][H]>CO.[Ni]>[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[NH2:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

참가 물질

5

반응물 2

HCID 150681131-(Hexyloxy)-2-nitrobenzeneHCID 178418361HCID 178418361, 화합물2회

생성물 1

HCID 159374522-(Hexyloxy)aniline

시약·촉매·용매 2

HCID 935Nickel촉매HCID 887Methanol용매

실험 절차

1-(Hexyloxy)-2-nitrobenzene, 61.28 g (0.27 mol) is dissolved in 700 ml of methanol, 3 g Raney nickel is added and the mixture exposed to hydrogen gas until the required amount of hydrogen is absorbed. The methanol solution is filtered and concentrated in vacuo and the residue distilled to give 50 g of 2-(hexyloxy)benzenamine; bp 145°-148° C. at 4 mm.

후처리

  1. customis absorbed
  2. filtrationThe methanol solution is filtered
  3. concentrationconcentrated in vacuo
  4. distillationthe residue distilled

출처 및 근거

ORD 기록
ord-0280dc5bb5ee423ab0767d93426a37c5
출처 데이터셋
uspto-grants-1989_11
특허 번호
US04882357

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