Ethanol → Sodium ZINC monocetylphosphate

HRID 1645753

반응식

HRID 1645753 반응식
[CH2:1]([O:17][P:18](=[O:21])([OH:20])[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].C(O)C.[OH-].[Na+:26].O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Zn+2:39]>O>[CH2:1]([O:17][P:18]([O-:21])([O-:20])=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[Zn+2:39].[Na+:26]

참가 물질

6

반응물 4

HCID 702EthanolHCID 14798Sodium Hydroxide2회HCID 19059Hexadecyl phosphateHCID 62640Zinc Sulfate Heptahydrate

생성물 1

HCID 22244895Sodium ZINC monocetylphosphate

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

50 g of monocetylphosphoric acid and 100 g of ethanol were placed in a 500 ml reaction vessel. Further, a solution of 6.29% of 96% sodium hydroxide (purity was taken into consideration by calculating it from the degree of neutralization determined by titration) dissolved in 200 g of ion-exchanged water was added thereto. After the temperature was elevated to 80° C., it was confirmed that they were clearly dissolved. The solution was continuously stirred for 30 minutes. A solution of 22.3 g of zinc sulfate heptahydrate dissolved in 100 g of ion-exchanged water was added dropwise thereto to carry out a salt exchange reaction. After the completion of the dropwise addition, the mixture was stirred for 30 minutes. 9.30 g of an aqueous solution of 33.33% sodium hydroxide was added dropwise thereto, to thereby adjust the pH of the reaction mixture to 5. Further, the mixture was stirred for one hour. After the completion of the reaction, the reaction mixture was cooled and the product was recovered by filtration, washed with water and dried, to obtain 51.2 g of the particles of sodium zinc monocetylphosphate.

후처리

  1. additionwas added
  2. customwas elevated to 80° C.
  3. dissolutionwere clearly dissolved
  4. additionwas added dropwise
  5. customa salt exchange reaction
  6. additionAfter the completion of the dropwise addition
  7. stirringthe mixture was stirred for 30 minutes
  8. stirringFurther, the mixture was stirred for one hour
  9. customAfter the completion of the reaction
  10. temperaturethe reaction mixture was cooled
  11. filtrationthe product was recovered by filtration
  12. washwashed with water
  13. customdried

출처 및 근거

ORD 기록
ord-2899828e36d74aaf95a0a716f20d0588
출처 데이터셋
uspto-grants-1993_01
특허 번호
US05176904

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