Ethanol → Sodium ZINC monostearylphosphate

HRID 1645756

반응식

HRID 1645756 반응식
[CH2:1]([O:19][P:20](=[O:23])([OH:22])[OH:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].C(O)C.[OH-].[Na+:28].O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Zn+2:41]>O>[CH2:1]([O:19][P:20]([O-:23])([O-:22])=[O:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Zn+2:41].[Na+:28]

참가 물질

6

반응물 4

HCID 702EthanolHCID 14798Sodium Hydroxide2회HCID 62640Zinc Sulfate HeptahydrateHCID 76290Monostearyl phosphate

생성물 1

HCID 19772870Sodium ZINC monostearylphosphate

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

50 g of monostearylphosphoric acid and 100 g of ethanol were put into a 500 ml reaction vessel. Further, a solution of 5.94 g of 96% sodium hydroxide (purity was taken into consideration by calculating it from the degree of neutralization determined by titration) dissolved in 200 g of ion-exchanged water was added thereto. After the temperature was elevated to 80° C., it was confirmed that they were clearly dissolved. The solution was continuously stirred for 30 minutes. A solution of 21.4 g of zinc sulfate heptahydrate dissolved in 100 g of ion-exchanged water was added dropwise thereto to carry out a salt exchange reaction. After the completion of the addition, the mixture was stirred for 30 minutes. 8.85 g of an aqueous solution of 33.33% sodium hydroxide was added dropwise thereto to adjust the pH of the reaction mixture to 3. Further, the mixture was stirred for one hour. After the completion of the reaction, the mixture was cooled and the product was collected by filtration, washed with water and dried, to obtain 51.5 g of the particles of sodium zinc monostearylphosphate.

후처리

  1. additionwas added
  2. customwas elevated to 80° C.
  3. dissolutionwere clearly dissolved
  4. additionwas added dropwise
  5. customa salt exchange reaction
  6. additionAfter the completion of the addition
  7. stirringthe mixture was stirred for 30 minutes
  8. stirringFurther, the mixture was stirred for one hour
  9. customAfter the completion of the reaction
  10. temperaturethe mixture was cooled
  11. filtrationthe product was collected by filtration
  12. washwashed with water
  13. customdried

출처 및 근거

ORD 기록
ord-2b9f713557ef4921bd7b080a92080241
출처 데이터셋
uspto-grants-1993_01
특허 번호
US05176904

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