ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate → HCID 13072040, 화합물

HRID 1648935노트

반응식

HRID 1648935 반응식
[CH2:1]([N:8]1[CH2:14][CH2:13][C:12]2[CH:15]=[C:16]([C:18]([O:20][CH2:21][CH3:22])=[O:19])[S:17][C:11]=2[CH2:10][CH2:9]1)[C:2]1C=CC=CC=1>[Ni].C(O)C>[CH2:1]([N:8]1[CH2:14][CH2:13][C:12]2[CH:15]=[C:16]([C:18]([O:20][CH2:21][CH3:22])=[O:19])[S:17][C:11]=2[CH2:10][CH2:9]1)[CH3:2]

참가 물질

4

반응물 1

HCID 13072038ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate

생성물 1

HCID 13072040HCID 13072040, 화합물

시약·촉매·용매 2

HCID 935Nickel촉매HCID 702Ethanol용매

실험 절차

3.15 gm (0.01 mol) of ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate were refluxed with the same amount of Raney nickel in 50 ml of ethyl alcohol for 6 hours. The catalyst was then removed by suction filtering, and the filtrate was concentrated by evaporation.

후처리

  1. customThe catalyst was then removed by suction
  2. filtrationfiltering
  3. concentrationthe filtrate was concentrated by evaporation

출처 및 근거

ORD 기록
ord-024c7012f65d4a58a5092da722aa51a2
출처 데이터셋
uspto-grants-1983_11
특허 번호
US04414225

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