2,3-Dinitrotoluene → beta-Dipropylamino-2,3-dinitrostyrene

HRID 1650672

반응식

HRID 1650672 반응식
[N+:1]([C:4]1[C:9]([N+:10]([O-:12])=[O:11])=[CH:8][CH:7]=[CH:6][C:5]=1[CH3:13])([O-:3])=[O:2].[CH2:14]([N:17]([CH:21](N(CCC)CCC)OC(C)(C)C)[CH2:18][CH2:19][CH3:20])[CH2:15][CH3:16]>>[CH2:14]([N:17]([CH2:18][CH2:19][CH3:20])[CH:21]=[CH:13][C:5]1[CH:6]=[CH:7][CH:8]=[C:9]([N+:10]([O-:12])=[O:11])[C:4]=1[N+:1]([O-:3])=[O:2])[CH2:15][CH3:16]

참가 물질

3

반응물 2

HCID 117612,3-DinitrotolueneHCID 137713131-tert-Butoxy-N,N,N',N'-tetrapropylmethanediamine

생성물 1

HCID 54130656beta-Dipropylamino-2,3-dinitrostyrene수율 85.8%

실험 절차

For two hours, 5.5 g of 2,3-dinitrotoluene is heated with 13.0 g of bisdipropylamino-tert-butoxymethane to 60° C. After cooling, the reaction mixture is freed of volatile components under a high vacuum, thus obtaining 7.6 g of β-dipropylamino-2,3-dinitrostyrene as an oil.

후처리

  1. temperatureAfter cooling

출처 및 근거

ORD 기록
ord-beb7c777ba3f47c29ea191bf7f02fde5
출처 데이터셋
uspto-grants-1990_05
특허 번호
US04925854

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