Tetrafluoroethylene → HCID 178447915, 화합물

HRID 1653610노트

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HRID 1653610 반응식
[CH2:1]([C@H:4]1[CH2:9][CH2:8][C@H:7]([C:10]2[CH:15]=[CH:14][C:13]([OH:16])=[CH:12][CH:11]=2)[CH2:6][CH2:5]1)[CH2:2][CH3:3].[H-].[Na+].[F:19][C:20]([F:24])=[C:21](F)[F:22]>C1C=CC=CC=1.O1CCCC1>[CH2:1]([C@H:4]1[CH2:5][CH2:6][C@H:7]([C:10]2[CH:15]=[CH:14][C:13]([O:16][C:21]([F:22])=[C:20]([F:24])[F:19])=[CH:12][CH:11]=2)[CH2:8][CH2:9]1)[CH2:2][CH3:3]

참가 물질

6

반응물 3

HCID 8301TetrafluoroethyleneHCID 24758Sodium hydrideHCID 178447901HCID 178447901, 화합물

생성물 1

HCID 178447915HCID 178447915, 화합물

시약·촉매·용매 2

HCID 241Benzene용매HCID 8028Tetrahydrofuran용매

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온도
140 °C

실험 절차

A solution of 10 g of p-(trans-4-n-propylcyclohexyl)phenol in a mixture of 40 ml of benzene and 10 ml of tetrahydrofuran is reacted with sodium hydride analogously to Example 1. After tetrafluoroethene has been condensed in, the mixture is heated at 140° C. for about 20 hours and treated as described in Example 1. p-(trans-4-n-propylcyclohexyl)trifluorovinyloxybenzene is obtained.

후처리

  1. customcondensed in, the mixture
  2. additiontreated

출처 및 근거

ORD 기록
ord-ad8186fb5b77478cb16f6ce861a808d8
출처 데이터셋
uspto-grants-1995_04
특허 번호
US05403512

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