Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trifluoroiodoethylene → 4-[4-(4-Propylcyclohexyl)cyclohexyl]-1-(1,2,2-trifluorovinyl)benzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trifluoroiodoethylene | HCID 67755 | — |
| 반응물 | (trans,trans)-4-(4-Iodophenyl)-4'-propyl-1,1'-bi(cyclohexane) | HCID 13931028 | — |
| 촉매 | Zinc | HCID 23994 | — |
| 촉매 | HCID 178418397 | HCID 178418397 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 4-[4-(4-Propylcyclohexyl)cyclohexyl]-1-(1,2,2-trifluorovinyl)benzene | HCID 20080204 | — |
반응 단계
A mixture of 5.0 g (77 mmol) of zinc powder, 50 ml of THF and 13.5 g (65 mmol) of trifluoroiodoethylene is stirred overnight, initially with ice cooling, later at room temperature. 20.5 g (50 mmol) of 1-iodo-4-[4-(4-propylcyclohexyl)cyclohexyl]benzene and 1.1 g-of tetrakis(triphenylphosphine)palladium are then added.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05403512 |
| 출처 데이터셋 | uspto-grants-1995_04 |
| ORD ID | ord-9e3c7aec233d464aa7cfacce147fef7c |
| 출처 메모 | uspto-grants-1995_04 |