Sodium → 2-(2,3,6-trimethylphenylmethylthio)pyridine N-oxide

반응식

Br[CH2:2][C:3]1[C:4](=[C:6]([C:8](=[CH:10][CH:11]=1)[CH3:9])[CH3:7])[CH3:5].[SH:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][N+:14]=1[O-:19].[Na]>>[CH3:5][C:4]1[C:3]([CH3:2])=[CH:11][CH:10]=[C:8]([CH3:9])[C:6]=1[CH2:7][S:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][N+:14]=1[O-:19]

참가 물질

반응물 3

HCID 5360545Sodium

HCID 99907811-(Bromomethyl)-2,3,4-trimethylbenzene

HCID 178526253HCID 178526253, 화합물

생성물 1

HCID 540170112-(2,3,6-trimethylphenylmethylthio)pyridine N-oxide수율 50%

실험 절차

The intermediate 2-(2,3,6-trimethylphenylmethylthio)pyridine N-oxide is prepared from α2 -bromoprehnitene with 2-mercaptopyridine N-oxide, sodium salt by the procedure described in Example 2. Yield 50% theory. Melting point 108° - 110°C. Structure confirmed by IR and NMR.

출처 및 근거

ORD 기록: ord-f74bcc2bc54b429a8fcc3cf1c66832ae
출처 데이터셋: uspto-grants-1976_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03960542

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