Water → HCID 12770097, 화합물

HRID 1659445

반응식

HRID 1659445 반응식
CS[S:3][CH3:4].[CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH:6]=1.[OH2:11].[C:12](#[N:14])[CH3:13]>F[B-](F)(F)F.C([N+](CCCC)(CCCC)CCCC)CCC.[Pt]>[C:12]([NH:14][CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH:6]1[S:3][CH3:4])(=[O:11])[CH3:13]

참가 물질

7

반응물 4

HCID 962WaterHCID 6342AcetonitrileHCID 8079CyclohexeneHCID 12232Dimethyl Disulfide

생성물 1

HCID 12770097HCID 12770097, 화합물

시약·촉매·용매 2

HCID 23939Platinum촉매HCID 67932Tetrabutylammonium Tetrafluoroborate촉매

실험 절차

A mixture of dimethyldisulphide (96 mg) in acetonitrile containing cyclohexene (405 mg) was placed in a conventional H-type electrolytic cell. The cell was provided with a number 4 sintered glass frit as divider and with 1 sq. cm. platinum mesh cathode and anode. The potential measurement was made with respect to a Ag/Ag+ (0.01 M) reference electrode. Tetra-n-butyl ammonium fluoroborate (0.1 M) was added as electrolyte. A constant potential of 1.20 volts was maintained at the anode with a potentiostat until 2 coulomb equivalents of charge per mole of disulphide had been passed. Water was then added to the anolyte and the aqueous phase extracted with diethyl ether to yield 116 mg of 2-acetamido 1-methylthio cyclohexane. Mass Spec. m/e 187 (parent ion). I.R. 3290 & 1650 cm-1.

후처리

  1. customThe cell was provided with a number 4 sintered glass frit as divider and with 1 sq. cm
  2. temperatureA constant potential of 1.20 volts was maintained at the anode with a potentiostat until 2 coulomb equivalents
  3. extractionthe aqueous phase extracted with diethyl ether

출처 및 근거

ORD 기록
ord-cca45905f75849ea9cac28a2fe69eaf8
출처 데이터셋
uspto-grants-1981_12
특허 번호
US04304642

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